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Heterogeneous Catalysis

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Heterogeneous catalysis is an enormously broad field of study, encompassing every catalytic reaction between gas or liquid phases that occurs on the surface of a solid catalyst.

Ideal conditions for heterogeneous catalysis involve large surface areas per unit of catalyst.

Overview

The onset of microfabrication has enabled developers to manufacture metallic catalysts with extremely fine microstructural properties (finely divided sheets, gauzes, nanostructured films, etc.) which translates to a greater number of reactive sites, thus greater efficiency.

Heterogeneous Catalysis in Practice

Maleic Anhydride

Maleic anhydride (MA) is a widely produced chemical that derives from the partial oxidation of n-butane by air over vanadium pyrophosphate (VPP) catalyst. It is an extremely valuable compound that forms the basis of various elastomers, polyester resins, thermoplastics, and more, with limitless end-use manufacturing capabilities. Research efforts into MA production are subsequently keenly focused on optimizing the benzene-vanadium catalysis routes.

Biomass Tar

Carbon neutrality is a stopgap measure aimed at offsetting the harmful greenhouse gas emissions from big industry, but the only way to tackle manmade climate change is to champion a cleaner alternative to fossil fuels. The problem is that few solutions are as energy-efficient as conventional combustion. Steam reformation of biomass tar could provide the answer to this problem. Current research into biomass tar reformation is focused mainly on resolving the deactivation of catalysts due to carbon formation at all available active sites.

Syngas

One of the most diverse methods of heterogeneous catalysis relies heavily on the use of syngas (synthesis gas), comprising a combination of carbon monoxide and hydrogen. This mixture is traditionally produced via the oxidation of coal with steam, or by partial oxidation of methane. The resultant gas species are useful in the production of fertilizers, fuels, solvents, and other synthetic materials.

Hiden Analytical’s Superior Systems

At Hiden Analytical, we offer an expansive range of gas analysis products suitable for characterizing myriad heterogeneous catalytic processes with far-reaching industrial applicability. Contact us to learn more.

 

Further Reading

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Tuning the selectivity of NH3 oxidation via cooperative electronic interactions between platinum and copper sites 18.35 MB 7 downloads

Tuning the selectivity of NH3 oxidation via cooperative electronic interactions between...
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Alkaline Earth Carbonate Engineered Pt Electronic States for High-Efficiency Propylene Oxidation at Low Temperatures 19.80 MB 1 downloads

Alkaline Earth Carbonate Engineered Pt Electronic States for High-Efficiency Propylene...
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Thermal degradation of impact-modified PMMA in mechanical and chemical recycling 3.22 MB 8 downloads

Thermal degradation of impact-modified PMMA in mechanical and chemical recycling ...
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The importance of gas purity in catalytic ammonia synthesis 3.71 MB 0 downloads

The importance of gas purity in catalytic ammonia synthesis ...
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CeO2 Promoted CuO/MgO-Al2O3 Catalyst with Enhanced Activity and Water-Resistance for CO Oxidation 7.69 MB 0 downloads

CeO2 Promoted CuO/MgO-Al2O3 Catalyst with Enhanced Activity and Water-Resistance...
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Distinctly different active sites of ZnO-ZrO2 catalysts in CO2 and CO hydrogenation to methanol reactions 30.23 MB 3 downloads

Distinctly different active sites of ZnO-ZrO2 catalysts in CO2 and CO hydrogenation...
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Experimental Study on Ammonia Dissociation and NOx Emission Under Fuel-Rich Combustion in a Porous Burner 3.39 MB 6 downloads

Experimental Study on Ammonia Dissociation and NOx Emission Under Fuel-Rich Combustion...
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Suppressing Jahn-Teller distortion of MnO2 via B-Ni dual single-atoms integration for methane catalytic combustion 3.39 MB 0 downloads

Suppressing Jahn-Teller distortion of MnO2 via B-Ni dual single-atoms integration...
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Insights into the role of Pt promoter in Co/TiO2 catalysts for CO hydrogenation 21.74 MB 2 downloads

Insights into the role of Pt promoter in Co/TiO2 catalysts for CO hydrogenation ...
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Tuning the Selectivity in the Nonoxidative Alkane Dehydrogenation Reaction by Potassium-Promoted Zeolite-Encapsulated Pt Catalysts 11.92 MB 2 downloads

Tuning the Selectivity in the Nonoxidative Alkane Dehydrogenation Reaction by Potassium-Promoted...