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Cathode Studies

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Cathode studies largely focus on exploring the use of new and improved materials suitable for energy storage applications.

The underlying materials used for electrodes have a dramatic influence on battery performance. Scientists continue to improve techniques for development of traditional lithium Ion batteries but research is also focused on sustainable alternatives to cathode materials.   

Overview

In a disposable battery, it is enough for electrodes to flow in a single direction; from the negatively-charged (-ve) anode to the positively-charged (+ve) cathode. Rechargeable batteries need to be able to reverse that flow. Lithium was identified as the ideal substance for both electrodes in a rechargeable cell as it can readily accept and/or lose electrons depending the configuration of the electrode element.

Hiden Analytical is one of the world’s leading suppliers of differential electrochemical mass spectrometry (DEMS) solutions for advanced cathode studies and lithium-ion (li-ion) battery research. This is a critical area of research and development for sustainable energy storage devices lightweight enough to support a range of mobile electronics applications.

Cathode Characterisation: New Structural Materials

The true impact of cathode materials on li-ion battery performance was demonstrated by a joint team of chemists who were awarded with the Nobel Prize for Chemistry in 2019 for their efforts. They suggested replacing potentially hazardous lithium metal elements with novel electrodes based on lithium ions immobilised in a metal sulphide framework. This mitigated the potential explosivity of lithium metal elements if exposed to air, while subsequently doubling energy capacity.

High energy, high power cathode materials that can facilitate both discharge and recharge cycles through variable ion and electron transportation are now an intensive area of research. Numerous structural groups are currently under consideration for next-gen energy storage devices, and DEMS is one of the leading solutions for advanced cathode studies.

The Hiden DEMS instrument is compatible with a near limitless range of electrode and electrolytes to support the broadest possible scope of materials research. Contact us today for more information about our mass spectrometry solutions for surveying different combinations of electrodes and electrolytes.

Further Reading

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Singlet oxygen in non-aqueous oxygen redox: direct spectroscopic evidence for formation pathways and reliability of chemical probes 822.33 KB 9 downloads

Singlet oxygen in non-aqueous oxygen redox: direct spectroscopic evidence for formation...
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Bridging the Gap Between Microstructurally Resolved Computed Tomography-Based and Homogenised Doyle-Fuller-Newman Models for Lithium-Ion Batteries 4.64 MB 18 downloads

Bridging the Gap Between Microstructurally Resolved Computed Tomography-Based and Homogenised...
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Priority Lithium recovery from spent Li-ion batteries via carbothermal reduction with water leaching 6.57 MB 28 downloads

Priority Lithium recovery from spent Li-ion batteries via carbothermal reduction...
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Gas induced formation of inactive Li in rechargeable lithium metal batteries 1.47 MB 31 downloads

Gas induced formation of inactive Li in rechargeable lithium metal batteries ...
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Stabilizing oxygen by high‐valance element doping for high‐performance Li‐rich layered oxides 68.00 KB 0 downloads

Stabilizing oxygen by high‐valance element doping for high‐performance Li‐rich...
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Oxygen Anion Redox Chemistry Correlated with Spin State in Ni-Rich Layered Cathodes 4.28 MB 29 downloads

Oxygen Anion Redox Chemistry Correlated with Spin State in Ni-Rich Layered Cathodes ...
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Mastering the synergy between Na3V2(PO4)2F3 electrode and electrolyte: A must for Na-ion cells 2.60 MB 27 downloads

Mastering the synergy between Na3V2(PO4)2F3 electrode and electrolyte: A must for...
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Regio-isomerism Directed Electrocatalysis for Energy Efficient Zinc-air Battery 4.53 MB 28 downloads

Regio-isomerism Directed Electrocatalysis for Energy Efficient Zinc-air Battery ...
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Controlling Li Dendritic Growth in Graphite Anodes by Potassium Electrolyte Additives for Li-Ion Batteries 3.75 MB 59 downloads

Controlling Li Dendritic Growth in Graphite Anodes by Potassium Electrolyte Additives...