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Heterogeneous Catalysis

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Heterogeneous catalysis is an enormously broad field of study, encompassing every catalytic reaction between gas or liquid phases that occurs on the surface of a solid catalyst.

Ideal conditions for heterogeneous catalysis involve large surface areas per unit of catalyst.

Overview

The onset of microfabrication has enabled developers to manufacture metallic catalysts with extremely fine microstructural properties (finely divided sheets, gauzes, nanostructured films, etc.) which translates to a greater number of reactive sites, thus greater efficiency.

Heterogeneous Catalysis in Practice

Maleic Anhydride

Maleic anhydride (MA) is a widely produced chemical that derives from the partial oxidation of n-butane by air over vanadium pyrophosphate (VPP) catalyst. It is an extremely valuable compound that forms the basis of various elastomers, polyester resins, thermoplastics, and more, with limitless end-use manufacturing capabilities. Research efforts into MA production are subsequently keenly focused on optimizing the benzene-vanadium catalysis routes.

Biomass Tar

Carbon neutrality is a stopgap measure aimed at offsetting the harmful greenhouse gas emissions from big industry, but the only way to tackle manmade climate change is to champion a cleaner alternative to fossil fuels. The problem is that few solutions are as energy-efficient as conventional combustion. Steam reformation of biomass tar could provide the answer to this problem. Current research into biomass tar reformation is focused mainly on resolving the deactivation of catalysts due to carbon formation at all available active sites.

Syngas

One of the most diverse methods of heterogeneous catalysis relies heavily on the use of syngas (synthesis gas), comprising a combination of carbon monoxide and hydrogen. This mixture is traditionally produced via the oxidation of coal with steam, or by partial oxidation of methane. The resultant gas species are useful in the production of fertilizers, fuels, solvents, and other synthetic materials.

Hiden Analytical’s Superior Systems

At Hiden Analytical, we offer an expansive range of gas analysis products suitable for characterizing myriad heterogeneous catalytic processes with far-reaching industrial applicability. Contact us to learn more.

 

Further Reading

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Methane Conversion to Methanol Using Au/ZSM‑5 is Promoted by Carbon 4.20 MB 14 downloads

Methane Conversion to Methanol Using Au/ZSM‑5 is Promoted by Carbon ...
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Co-existence of atomically dispersed Ru and Ce3+ sites is responsible for excellent low temperature N2O reduction activity of Ru/CeO2 1.11 MB 10 downloads

Co-existence of atomically dispersed Ru and Ce3+ sites is responsible for excellent...
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Copper nanoparticles encapsulated in zeolitic imidazolate framework-8 as a highly stable and selective catalyst for CO2 hydrogenation to methanol 2.77 MB 11 downloads

Copper nanoparticles encapsulated in zeolitic imidazolate framework-8 as a highly...
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Mechanistic Insights into the Photocatalytic Hydrogen Production of Y5 and Y6 Nanoparticles 3.15 MB 9 downloads

Mechanistic Insights into the Photocatalytic Hydrogen Production of Y5 and Y6 Nanoparticles ...
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CO2 hydrogenation to light olefins using In2O3 and SSZ-13 catalyst − Understanding the role of zeolite acidity in olefin production 8.84 MB 9 downloads

CO2 hydrogenation to light olefins using In2O3 and SSZ-13 catalyst − Understanding...
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Identification of reversible and irreversible deactivation of MDA catalysts: a key to design a viable process 2.59 MB 12 downloads

Identification of reversible and irreversible deactivation of MDA catalysts: a key...
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Generation of Subnanometer Metal Clusters in Silicoaluminate Zeolites as Bifunctional Catalysts 11.86 MB 12 downloads

Generation of Subnanometer Metal Clusters in Silicoaluminate Zeolites as Bifunctional...
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Cu and Co-modified SrTiO3 as materials for environmental applications 10.27 MB 12 downloads

Cu and Co-modified SrTiO3 as materials for environmental applications ...
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Boosting the Hydrodeoxygenation Activity and Selectivity of Ni/(M)- SBA-15 Catalysts by Chemical Alteration of the Support 5.99 MB 11 downloads

Boosting the Hydrodeoxygenation Activity and Selectivity of Ni/(M)-SBA-15 Catalysts...